Two errors, and whose fault they are
The exact answer to a nearby problem
A good algorithm does not give an approximate answer to your problem. It gives the exact answer to a problem very close to yours — and once that is the definition, a wrong result has two possible authors and they can be measured apart.
A small residual is not a small error
Substituting the answer back and finding that it fits is the most natural check there is, and it verifies the wrong thing. A residual of 10⁻¹⁷ is entirely compatible with an answer whose second digit is wrong.
The condition number is an amplifier
κ is usually introduced as a definition and then quoted. It is a measurement: perturb the input by a known amount, look at how much the output moves, and the largest ratio you can find is the number.
An answer that is known
Almost every demonstration of numerical error estimates the error by computing the same thing more carefully. The Hilbert matrix does not need that: its inverse is a closed form in integers, so the true answer is available exactly and the error is measured rather than approximated.